2012
Journal article
Open Access
Carbon nanohorn-based nanofluids: characterization of the spectral scattering albedo
Mercatelli Luca, Sani Elisa, Giannini Annalisa, Di Ninni Paola, Martelli Fabrizio, Zaccanti Giovanni
Condensed Matter Physics Materials Science(all) ABSORPTION General Materials Science Nano Express
The full characterization of the optical properties of nanofluids consisting of single-wall carbon nanohorns of different morphologies in aqueous suspensions is carried out using a novel spectrophotometric technique. Information on the nanofluid scattering and absorption spectral characteristics is obtained by analyzing the data within the single scattering theory and validating the method by comparison with previous monochromatic measurements performed with a different technique. The high absorption coefficient measured joint to the very low scattering albedo opens promising application perspectives for single-wall carbon nanohorn-based fluid or solid suspensions. The proposed approximate approach can be extended also to other low-scattering turbid media.
Source: Nanoscale research letters (Online) 7 (2012): 96–96. doi:10.1186/1556-276X-7-96
Publisher: Springer Verlag New York,, Seacaucus, NJ , Stati Uniti d'America
Iijima, S, Yudasaka, M, Yamada, R, Bandow, S, Suenaga, K, Kokai, F, Takahashi, K. Nano-aggregates of single-walled graphitic carbon nano-horns. Chem Phys Letters. 1999; 309: 165-170
Murata, K, Kaneko, K, Kokai, F, Takahashi, K, Yudasaka, M, Iijima, S. Pore structure of single-wall carbon nanohorn aggregates. Chem Phys Letters. 2000; 331: 14-20
Yudasaka, M, Iijima, S, Crespi, VH. Single-wall carbon nanohorns and nanocones. Carbon Nanotubes Topics in Applied Physics. 2008; 111: 605-629
Fan, X, Tan, J, Zhang, G, Zhang, F. Isolation of carbon nanohorn assemblies and their potential for intracellular delivery. Nanotechnology. 2007; 18: 195103
Bekyarova, E, Murata, K, Yudasaka, M, Kasuya, D, Iijima, S, Tanaka, H, Kahoh, H, Kaneko, K. Single-wall nanostructured carbon for methane storage. J Phys Chem B. 2003; 107: 4682-4684
Ajima, K, Yudasaka, M, Murakami, T, Maigne, A, Shiba, K, Iijima, S. Carbon nanohorns as anticancer drug carriers. Mol Pharm. 2005; 2: 475-480
Sani, E, Barison, S, Pagura, C, Mercatelli, L, Sansoni, P, Fontani, D, Jafrancesco, D, Francini, F. Carbon nanohorns-based nanofluids as direct sunlight absorbers. Opt Expr. 2000; 18: 5180-5187
Mercatelli, L, Sani, E, Zaccanti, G, Martelli, F, Di Ninni, P, Barison, S, Pagura, C, Agresti, F, Jafrancesco, D. Absorption and scattering properties of carbon nanohorn-based nanofluids for direct sunlight absorbers. Nanoscale Res Lett. 2011; 6: 282
Lynch, RM, Voy, BH, Glass, DF, Mahurin, SM, Zhao, B, Hu, H, Saxton, AM, Donnell, RL, Cheng, MD. Assessing the pulmonary toxicity of single-walled carbon nanohorns. Nanotoxicology. 2007; 1: 157-166
Pagona, G, Sandanayaka, ASD, Araki, Y, Fan, J, Tagmatarchis, N, Yudasaka, M, Iijima, S, Ito, O. Electronic interplay on illuminated aqueous carbon nanohorn-porphyrin ensembles. J Phys Chem B. 2006; 110: 20729-20732
Sani, E, Mercatelli, L, Barison, S, Pagura, C, Agresti, F, Colla, L, Sansoni, P. Potential of carbon nanohorn-based suspensions for solar thermal collectors. Sol Energ Mater Sol Cell. 2011; 95: 2994-3000
Mercatelli, L, Sani, E, Fontani, D, Zaccanti, G, Martelli, F, Di Ninni, P. Scattering and absorption properties of carbon nanohorn-based nanofluids for solar energy applications. J Eur Opt Soc-Rapid Publ. 2011; 6: 11025
Schiavon, M. Device and method for production of carbon nanotubes, fullerene and their derivatives.
Fedele, L, Colla, L, Bobbo, S, Barison, S, Agresti, F. Experimental stability analysis of different water-based nanofluids. Nanoscale Res Lett. 2011; 6: 300
Zaccanti, G, Bruscaglioni, P. Deviation from the Lambert-Beer law in the transmittance of a light beam through diffusing media: experimental results. J Modern Opt. 1988; 35: 229-242
Martelli, F, Del Bianco, S, Ismaelli, A, Zaccanti, G. Light Propagation Through Biological Tissue and Other Diffusive Media: Theory, Solutions, and Software. 2010
Di Ninni, P, Martelli, F, Zaccanti, G. The use of India ink in tissue-simulating phantoms. Opt Expr. 2010; 18: 26854-65
1. Iijima S, Yudasaka M, Yamada R, Bandow S, Suenaga K, Kokai F, Takahashi K: Nano-aggregates of single-walled graphitic carbon nano-horns. Chem Phys Letters 1999, 309:165-170.
2. Murata K, Kaneko K, Kokai F, Takahashi K, Yudasaka M, Iijima S: Pore structure of single-wall carbon nanohorn aggregates. Chem Phys Letters 2000, 331:14-20.
3. Yudasaka M, Iijima S, Crespi VH: Single-wall carbon nanohorns and nanocones. In Carbon Nanotubes Topics in Applied Physics. Volume 111. Edited by: Jorio A, Dresselhaus G, Dresselhaus MS. Berlin/Heidelberg: Springer; 2008:605-629.
4. Fan X, Tan J, Zhang G, Zhang F: Isolation of carbon nanohorn assemblies and their potential for intracellular delivery. Nanotechnology 2007, 18:195103.
5. Bekyarova E, Murata K, Yudasaka M, Kasuya D, Iijima S, Tanaka H, Kahoh H, Kaneko K: Single-wall nanostructured carbon for methane storage. J Phys Chem B 2003, 107:4682-4684.
6. Ajima K, Yudasaka M, Murakami T, Maigne A, Shiba K, Iijima S: Carbon nanohorns as anticancer drug carriers. Mol Pharm 2005, 2:475-480.
7. Sani E, Barison S, Pagura C, Mercatelli L, Sansoni P, Fontani D, Jafrancesco D, Francini F: Carbon nanohorns-based nanofluids as direct sunlight absorbers. Opt Expr 2000, 18:5180-5187.
8. Mercatelli L, Sani E, Zaccanti G, Martelli F, Di Ninni P, Barison S, Pagura C, Agresti F, Jafrancesco D: Absorption and scattering properties of carbon nanohorn-based nanofluids for direct sunlight absorbers. Nanoscale Res Lett 2011, 6:282.
9. Lynch RM, Voy BH, Glass DF, Mahurin SM, Zhao B, Hu H, Saxton AM, Donnell RL, Cheng MD: Assessing the pulmonary toxicity of single-walled carbon nanohorns. Nanotoxicology 2007, 1:157-166.
10. Pagona G, Sandanayaka ASD, Araki Y, Fan J, Tagmatarchis N, Yudasaka M, Iijima S, Ito O: Electronic interplay on illuminated aqueous carbon nanohorn-porphyrin ensembles. J Phys Chem B 2006, 110:20729-20732.
11. Sani E, Mercatelli L, Barison S, Pagura C, Agresti F, Colla L, Sansoni P: Potential of carbon nanohorn-based suspensions for solar thermal collectors. Sol Energ Mater Sol Cell 2011, 95:2994-3000.
12. Mercatelli L, Sani E, Fontani D, Zaccanti G, Martelli F, Di Ninni P: Scattering and absorption properties of carbon nanohorn-based nanofluids for solar energy applications. J Eur Opt Soc-Rapid Publ 2011, 6:11025.
13. Schiavon M: Device and method for production of carbon nanotubes, fullerene and their derivatives , U.S. Patent 7, 125,525; EP 1428794.
14. Fedele L, Colla L, Bobbo S, Barison S, Agresti F: Experimental stability analysis of different water-based nanofluids. Nanoscale Res Lett 2011, 6:300.
15. Zaccanti G, Bruscaglioni P: Deviation from the Lambert-Beer law in the transmittance of a light beam through diffusing media: experimental results. J Modern Opt 1988, 35:229-242.
16. Martelli F, Del Bianco S, Ismaelli A, Zaccanti G: Light Propagation Through Biological Tissue and Other Diffusive Media: Theory, Solutions, and Software Bellingham: SPIE Press; 2010.
17. Di Ninni P, Martelli F, Zaccanti G: The use of India ink in tissue-simulating phantoms. Opt Expr 2010, 18:26854-65.
Murata, K, Kaneko, K, Kokai, F, Takahashi, K, Yudasaka, M, Iijima, S. Pore structure of single-wall carbon nanohorn aggregates. Chem Phys Letters. 2000; 331: 14-20
Yudasaka, M, Iijima, S, Crespi, VH. Single-wall carbon nanohorns and nanocones. Carbon Nanotubes Topics in Applied Physics. 2008; 111: 605-629
Fan, X, Tan, J, Zhang, G, Zhang, F. Isolation of carbon nanohorn assemblies and their potential for intracellular delivery. Nanotechnology. 2007; 18: 195103
Bekyarova, E, Murata, K, Yudasaka, M, Kasuya, D, Iijima, S, Tanaka, H, Kahoh, H, Kaneko, K. Single-wall nanostructured carbon for methane storage. J Phys Chem B. 2003; 107: 4682-4684
Ajima, K, Yudasaka, M, Murakami, T, Maigne, A, Shiba, K, Iijima, S. Carbon nanohorns as anticancer drug carriers. Mol Pharm. 2005; 2: 475-480
Sani, E, Barison, S, Pagura, C, Mercatelli, L, Sansoni, P, Fontani, D, Jafrancesco, D, Francini, F. Carbon nanohorns-based nanofluids as direct sunlight absorbers. Opt Expr. 2000; 18: 5180-5187
Mercatelli, L, Sani, E, Zaccanti, G, Martelli, F, Di Ninni, P, Barison, S, Pagura, C, Agresti, F, Jafrancesco, D. Absorption and scattering properties of carbon nanohorn-based nanofluids for direct sunlight absorbers. Nanoscale Res Lett. 2011; 6: 282
Lynch, RM, Voy, BH, Glass, DF, Mahurin, SM, Zhao, B, Hu, H, Saxton, AM, Donnell, RL, Cheng, MD. Assessing the pulmonary toxicity of single-walled carbon nanohorns. Nanotoxicology. 2007; 1: 157-166
Pagona, G, Sandanayaka, ASD, Araki, Y, Fan, J, Tagmatarchis, N, Yudasaka, M, Iijima, S, Ito, O. Electronic interplay on illuminated aqueous carbon nanohorn-porphyrin ensembles. J Phys Chem B. 2006; 110: 20729-20732
Sani, E, Mercatelli, L, Barison, S, Pagura, C, Agresti, F, Colla, L, Sansoni, P. Potential of carbon nanohorn-based suspensions for solar thermal collectors. Sol Energ Mater Sol Cell. 2011; 95: 2994-3000
Mercatelli, L, Sani, E, Fontani, D, Zaccanti, G, Martelli, F, Di Ninni, P. Scattering and absorption properties of carbon nanohorn-based nanofluids for solar energy applications. J Eur Opt Soc-Rapid Publ. 2011; 6: 11025
Schiavon, M. Device and method for production of carbon nanotubes, fullerene and their derivatives.
Fedele, L, Colla, L, Bobbo, S, Barison, S, Agresti, F. Experimental stability analysis of different water-based nanofluids. Nanoscale Res Lett. 2011; 6: 300
Zaccanti, G, Bruscaglioni, P. Deviation from the Lambert-Beer law in the transmittance of a light beam through diffusing media: experimental results. J Modern Opt. 1988; 35: 229-242
Martelli, F, Del Bianco, S, Ismaelli, A, Zaccanti, G. Light Propagation Through Biological Tissue and Other Diffusive Media: Theory, Solutions, and Software. 2010
Di Ninni, P, Martelli, F, Zaccanti, G. The use of India ink in tissue-simulating phantoms. Opt Expr. 2010; 18: 26854-65
1. Iijima S, Yudasaka M, Yamada R, Bandow S, Suenaga K, Kokai F, Takahashi K: Nano-aggregates of single-walled graphitic carbon nano-horns. Chem Phys Letters 1999, 309:165-170.
2. Murata K, Kaneko K, Kokai F, Takahashi K, Yudasaka M, Iijima S: Pore structure of single-wall carbon nanohorn aggregates. Chem Phys Letters 2000, 331:14-20.
3. Yudasaka M, Iijima S, Crespi VH: Single-wall carbon nanohorns and nanocones. In Carbon Nanotubes Topics in Applied Physics. Volume 111. Edited by: Jorio A, Dresselhaus G, Dresselhaus MS. Berlin/Heidelberg: Springer; 2008:605-629.
4. Fan X, Tan J, Zhang G, Zhang F: Isolation of carbon nanohorn assemblies and their potential for intracellular delivery. Nanotechnology 2007, 18:195103.
5. Bekyarova E, Murata K, Yudasaka M, Kasuya D, Iijima S, Tanaka H, Kahoh H, Kaneko K: Single-wall nanostructured carbon for methane storage. J Phys Chem B 2003, 107:4682-4684.
6. Ajima K, Yudasaka M, Murakami T, Maigne A, Shiba K, Iijima S: Carbon nanohorns as anticancer drug carriers. Mol Pharm 2005, 2:475-480.
7. Sani E, Barison S, Pagura C, Mercatelli L, Sansoni P, Fontani D, Jafrancesco D, Francini F: Carbon nanohorns-based nanofluids as direct sunlight absorbers. Opt Expr 2000, 18:5180-5187.
8. Mercatelli L, Sani E, Zaccanti G, Martelli F, Di Ninni P, Barison S, Pagura C, Agresti F, Jafrancesco D: Absorption and scattering properties of carbon nanohorn-based nanofluids for direct sunlight absorbers. Nanoscale Res Lett 2011, 6:282.
9. Lynch RM, Voy BH, Glass DF, Mahurin SM, Zhao B, Hu H, Saxton AM, Donnell RL, Cheng MD: Assessing the pulmonary toxicity of single-walled carbon nanohorns. Nanotoxicology 2007, 1:157-166.
10. Pagona G, Sandanayaka ASD, Araki Y, Fan J, Tagmatarchis N, Yudasaka M, Iijima S, Ito O: Electronic interplay on illuminated aqueous carbon nanohorn-porphyrin ensembles. J Phys Chem B 2006, 110:20729-20732.
11. Sani E, Mercatelli L, Barison S, Pagura C, Agresti F, Colla L, Sansoni P: Potential of carbon nanohorn-based suspensions for solar thermal collectors. Sol Energ Mater Sol Cell 2011, 95:2994-3000.
12. Mercatelli L, Sani E, Fontani D, Zaccanti G, Martelli F, Di Ninni P: Scattering and absorption properties of carbon nanohorn-based nanofluids for solar energy applications. J Eur Opt Soc-Rapid Publ 2011, 6:11025.
13. Schiavon M: Device and method for production of carbon nanotubes, fullerene and their derivatives , U.S. Patent 7, 125,525; EP 1428794.
14. Fedele L, Colla L, Bobbo S, Barison S, Agresti F: Experimental stability analysis of different water-based nanofluids. Nanoscale Res Lett 2011, 6:300.
15. Zaccanti G, Bruscaglioni P: Deviation from the Lambert-Beer law in the transmittance of a light beam through diffusing media: experimental results. J Modern Opt 1988, 35:229-242.
16. Martelli F, Del Bianco S, Ismaelli A, Zaccanti G: Light Propagation Through Biological Tissue and Other Diffusive Media: Theory, Solutions, and Software Bellingham: SPIE Press; 2010.
17. Di Ninni P, Martelli F, Zaccanti G: The use of India ink in tissue-simulating phantoms. Opt Expr 2010, 18:26854-65.
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@article{oai:it.cnr:prodotti:186615,
title = {Carbon nanohorn-based nanofluids: characterization of the spectral scattering albedo},
author = {Mercatelli Luca and Sani Elisa and Giannini Annalisa and Di Ninni Paola and Martelli Fabrizio and Zaccanti Giovanni},
publisher = {Springer Verlag New York,, Seacaucus, NJ , Stati Uniti d'America},
doi = {10.1186/1556-276x-7-96},
journal = {Nanoscale research letters (Online)},
volume = {7},
pages = {96–96},
year = {2012}
}CNR ExploRA
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